{"id":11894,"date":"2017-04-04T06:06:12","date_gmt":"2017-04-04T06:06:12","guid":{"rendered":"http:\/\/revoscience.com\/en\/?p=11894"},"modified":"2017-04-04T06:06:12","modified_gmt":"2017-04-04T06:06:12","slug":"researchers-iron-graphenes-wrinkles","status":"publish","type":"post","link":"https:\/\/www.revoscience.com\/en\/researchers-iron-graphenes-wrinkles\/","title":{"rendered":"Researchers \u201ciron out\u201d graphene\u2019s wrinkles"},"content":{"rendered":"

New technique produces highly conductive graphene wafers.<\/strong><\/em><\/span><\/p>\n

\"\"
Researchers at MIT have found a way to make graphene with fewer wrinkles, and to iron out the wrinkles that do appear. They found each wafer exhibited uniform performance, meaning that electrons flowed freely across each wafer, at similar speeds, even across previously wrinkled regions.<\/figcaption><\/figure>\n

CAMBRIDGE, Mass. —\u00a0From an electron\u2019s point of view, graphene must be a hair-raising thrill ride. For years, scientists have observed that electrons can blitz through graphene at velocities approaching the speed of light, far faster than they can travel through silicon and other semiconducting materials.<\/span><\/p>\n

Graphene, therefore, has been touted as a promising successor to silicon, with the potential to enable faster, more efficient electronic and photonic devices.<\/span><\/p>\n

But manufacturing pristine graphene \u2014 a single, perfectly flat, ultrathin sheet of carbon atoms, precisely aligned and linked together like chickenwire \u2014 is extremely difficult. Conventional fabrication processes often generate wrinkles, which can derail an electron\u2019s bullet-train journey, significantly limiting graphene\u2019s electrical performance.<\/span><\/p>\n

Now engineers at MIT have found a way to make graphene with fewer wrinkles, and to iron out the wrinkles that do appear. After fabricating and then flattening out the graphene, the researchers tested its electrical conductivity. They found each wafer exhibited uniform performance, meaning that electrons flowed freely across each wafer, at similar speeds, even across previously wrinkled regions.<\/span><\/p>\n

In a<\/span> paper<\/a> published today in the Proceedings of the National Academy of Sciences<\/em>, the researchers report that their techniques successfully produce wafer-scale, \u201csingle-domain\u201d graphene \u2014 single layers of graphene that are uniform in both atomic arrangement and electronic performance.<\/span><\/p>\n

\u201cFor graphene to play as a main semiconductor material for industry, it has to be single-domain, so that if you make millions of devices on it, the performance of the devices is the same in any location,\u201d says Jeehwan Kim, the Class of 1947 Career Development Assistant Professor in the departments of Mechanical Engineering and Materials Science and Engineering at MIT. \u201cNow we can really produce single-domain graphene at wafer scale.\u201d<\/span><\/p>\n

Kim\u2019s co-authors include Sanghoon Bae, Samuel Cruz, and Yunjo Kim from MIT, along with researchers from IBM, the University of California at Los Angeles, and Kyungpook National University in South Korea.<\/span><\/p>\n

A patchwork of wrinkles<\/strong><\/span><\/p>\n

The most common way to make graphene involves chemical vapor deposition, or CVD, a process in which carbon atoms are deposited onto a crystalline substrate such as copper foil. Once the copper foil is evenly coated with a single layer of carbon atoms, scientists submerge the entire thing in acid to etch away the copper. What remains is a single sheet of graphene, which researchers then pull out from the acid.<\/span><\/p>\n

The CVD process can produce relatively large, macroscropic wrinkles in graphene, due to the roughness of the underlying copper itself and the process of pulling the graphene out from the acid. The alignment of carbon atoms is not uniform across the graphene, creating a \u201cpolycrystalline\u201d state in which graphene resembles an uneven, patchwork terrain, preventing electrons from flowing at uniform rates.<\/span><\/p>\n

In 2013, while working at IBM, Kim and his colleagues developed a method to fabricate wafers of single-crystalline graphene, in which the orientation of carbon atoms is exactly the same throughout a wafer.<\/span><\/p>\n

Rather than using CVD, his team produced single-crystalline graphene from a silicon carbide wafer with an atomically smooth surface, albeit with tiny, step-like wrinkles on the order of several nanometers. They then used a thin sheet of nickel to peel off the topmost graphene from the silicon carbide wafer, in a process called layer-resolved graphene transfer.<\/span><\/p>\n

Ironing charges<\/strong><\/span><\/p>\n

In their new paper, Kim and his colleagues discovered that the layer-resolved graphene transfer irons out the steps and tiny wrinkles in silicon carbide-fabricated graphene. Before transferring the layer of graphene onto a silicon wafer, the team oxidized the silicon, creating a layer of silicon dioxide that naturally exhibits electrostatic charges. When the researchers then deposited the graphene, the silicon dioxide effectively pulled graphene\u2019s carbon atoms down onto the wafer, flattening out its steps and wrinkles.<\/span><\/p>\n

Kim says this ironing method would not work on CVD-fabricated graphene, as the wrinkles generated through CVD are much larger, on the order of several microns.<\/span><\/p>\n

\u201cThe CVD process creates wrinkles that are too high to be ironed out,\u201d Kim notes. \u201cFor silicon carbide graphene, the wrinkles are just a few nanometers high, short enough to be flattened out.\u201d<\/span><\/p>\n

To test whether the flattened, single-crystalline graphene wafers were single-domain, the researchers fabricated tiny transistors on multiple sites on each wafer, including across previously wrinkled regions.<\/span><\/p>\n

\u201cWe measured electron mobility throughout the wafers, and their performance was comparable,\u201d Kim says. \u201cWhat\u2019s more, this mobility in ironed graphene is two times faster. So now we really have single-domain graphene, and its electrical quality is much higher [than graphene-attached silicon carbide].\u201d<\/span><\/p>\n

Kim says that while there are still challenges to adapting graphene for use in electronics, the group\u2019s results give researchers a blueprint for how to reliably manufacture pristine, single-domain, wrinkle-free graphene at wafer scale.<\/span><\/p>\n

\u201cIf you want to make any electronic device using graphene, you need to work with single-domain graphene,\u201d Kim says. \u201cThere\u2019s still a long way to go to make an operational transistor out of graphene. But we can now show the community guidelines for how you can make single-crystalline, single-domain graphene.\u201d<\/span><\/p>\n","protected":false},"excerpt":{"rendered":"

New technique produces highly conductive graphene wafers. CAMBRIDGE, Mass. —\u00a0From an electron\u2019s point of view, graphene must be a hair-raising thrill ride. For years, scientists have observed that electrons can blitz through graphene at velocities approaching the speed of light, far faster than they can travel through silicon and other semiconducting materials. Graphene, therefore, has […]<\/p>\n","protected":false},"author":6,"featured_media":11895,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[17],"tags":[],"class_list":["post-11894","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-research"],"featured_image_urls":{"full":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2017\/04\/MIT-Single-Domain_0.jpg",639,426,false],"thumbnail":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2017\/04\/MIT-Single-Domain_0-150x150.jpg",150,150,true],"medium":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2017\/04\/MIT-Single-Domain_0-300x200.jpg",300,200,true],"medium_large":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2017\/04\/MIT-Single-Domain_0.jpg",639,426,false],"large":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2017\/04\/MIT-Single-Domain_0.jpg",639,426,false],"1536x1536":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2017\/04\/MIT-Single-Domain_0.jpg",639,426,false],"2048x2048":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2017\/04\/MIT-Single-Domain_0.jpg",639,426,false],"ultp_layout_landscape_large":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2017\/04\/MIT-Single-Domain_0.jpg",639,426,false],"ultp_layout_landscape":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2017\/04\/MIT-Single-Domain_0.jpg",639,426,false],"ultp_layout_portrait":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2017\/04\/MIT-Single-Domain_0.jpg",600,400,false],"ultp_layout_square":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2017\/04\/MIT-Single-Domain_0.jpg",600,400,false],"newspaper-x-single-post":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2017\/04\/MIT-Single-Domain_0.jpg",639,426,false],"newspaper-x-recent-post-big":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2017\/04\/MIT-Single-Domain_0.jpg",540,360,false],"newspaper-x-recent-post-list-image":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2017\/04\/MIT-Single-Domain_0.jpg",95,63,false],"web-stories-poster-portrait":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2017\/04\/MIT-Single-Domain_0.jpg",639,426,false],"web-stories-publisher-logo":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2017\/04\/MIT-Single-Domain_0.jpg",96,64,false],"web-stories-thumbnail":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2017\/04\/MIT-Single-Domain_0.jpg",150,100,false]},"author_info":{"info":["Amrita Tuladhar"]},"category_info":"Research<\/a>","tag_info":"Research","comment_count":"0","_links":{"self":[{"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/posts\/11894","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/users\/6"}],"replies":[{"embeddable":true,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/comments?post=11894"}],"version-history":[{"count":0,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/posts\/11894\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/media\/11895"}],"wp:attachment":[{"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/media?parent=11894"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/categories?post=11894"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/tags?post=11894"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}