{"id":2221,"date":"2015-01-22T10:05:28","date_gmt":"2015-01-22T10:05:28","guid":{"rendered":"http:\/\/revoscience.com\/en\/?p=2221"},"modified":"2015-01-22T10:05:28","modified_gmt":"2015-01-22T10:05:28","slug":"sequestration-on-shaky-ground","status":"publish","type":"post","link":"https:\/\/www.revoscience.com\/en\/sequestration-on-shaky-ground\/","title":{"rendered":"Sequestration on shaky ground"},"content":{"rendered":"

Study finds a natural impediment to the long-term sequestration of carbon dioxide.<\/strong><\/em><\/span><\/p>\n

\"MIT-CO2-sequestration-01_0\"<\/a>CAMBRIDGE, Mass. —\u00a0Carbon sequestration promises to address greenhouse-gas emissions by capturing carbon dioxide from the atmosphere and injecting it deep below the Earth\u2019s surface, where it would permanently solidify into rock. The U.S. Environmental Protection Agency estimates that current carbon-sequestration technologies may eliminate up to 90 percent of carbon dioxide emissions from coal-fired power plants.<\/span><\/p>\n

While such technologies may successfully remove greenhouse gases from the atmosphere, researchers in the Department of Earth, Atmospheric and Planetary Sciences at MIT have found that once injected into the ground, less carbon dioxide is converted to rock than previously imagined.<\/span><\/p>\n

The team studied the chemical reactions between carbon dioxide and its surroundings once the gas is injected into the Earth \u2014 finding that as carbon dioxide works its way underground, only a small fraction of the gas turns to rock. The remainder of the gas stays in a more tenuous form.<\/span><\/p>\n

\u201cIf it turns into rock, it\u2019s stable and will remain there permanently,\u201d says postdoc Yossi Cohen. \u201cHowever, if it stays in its gaseous or liquid phase, it remains mobile and it can possibly return back to the atmosphere.\u201d<\/span><\/p>\n

Cohen and Daniel Rothman, a professor of geophysics in MIT\u2019s Department of Earth, Atmospheric, and Planetary Sciences, detail the results this week in the journal\u00a0Proceedings of the Royal Society A.<\/em><\/span><\/p>\n

Current geologic carbon-sequestration techniques aim to inject carbon dioxide into the subsurface some 7,000 feet below the Earth\u2019s surface, a depth equivalent to more than five Empire State Buildings stacked end-to-end. At such depths, carbon dioxide may be stored in deep-saline aquifers: large pockets of brine that can chemically react with carbon dioxide to solidify the gas.<\/span><\/p>\n

Cohen and Rothman sought to model the chemical reactions that take place after carbon dioxide is injected into a briny, rocky environment. When carbon dioxide is pumped into the ground, it rushes into open pockets within rock, displacing any existing fluid, such as brine. What remains are bubbles of carbon dioxide, along with carbon dioxide dissolved in water. The dissolved carbon dioxide takes the form of bicarbonate and carbonic acid, which create an acidic environment. To precipitate, or solidify into rock, carbon dioxide requires a basic environment, such as brine.<\/span><\/p>\n

The researchers modeled the chemical reactions between two main regions: an acidic, low-pH region with a high concentration of carbon dioxide, and a higher-pH region filled with brine, or salty water. As each carbonate species reacts differently when diffusing or flowing through water, the researchers characterized each reaction, then worked each reaction into a reactive diffusion model \u2014 a simulation of chemical reactions as carbon dioxide flows through a briny, rocky environment.<\/span><\/p>\n

When the team analyzed the chemical reactions between regions rich in carbon dioxide and regions of brine, they found that the carbon dioxide solidifies \u2014 but only at the interface. The reaction essentially creates a solid wall at the point where carbon dioxide meets brine, keeping the bulk of the carbon dioxide from reacting with the brine.<\/span><\/p>\n

\u201cThis can basically close the channel, and no more material can move farther into the brine, because as soon as it touches the brine, it will become solid,\u201d Cohen says. \u201cThe expectation was that most of the carbon dioxide would become solid mineral. Our work suggests that significantly less will precipitate.\u201d<\/span><\/p>\n

Cohen and Rothman point out that their theoretical predictions require experimental study to determine the magnitude of this effect.<\/span><\/p>\n

\u201cExperiments would help determine the kind of rock that would minimize this clogging phenomenon,\u201d Cohen says. \u201cThere are many factors, such as the porosity and connectivity between pores in rocks, that will determine if and when carbon dioxide mineralizes. Our study reveals new features of this problem that may help identify the optimal geologic formations for long-term sequestration\u201d<\/span><\/p>\n

This research was funded in part by the U.S. Department of Energy.<\/span><\/p>\n

Key words<\/strong><\/p>\n

Sequestration:\u00a0the action of sequestrating or taking legal possession of assets;\u00a0the action of chemically \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 sequestering a substance.<\/span><\/p>\n

simulation:\u00a0<\/span>imitation or enactment, as of conditions anticipated;\u00a0<\/b>the act or process of pretending; feigning;\u00a0an \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 assumption or imitation of a particular appearance or form; counterfeit.<\/p>\n

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Study finds a natural impediment to the long-term sequestration of carbon dioxide. CAMBRIDGE, Mass. —\u00a0Carbon sequestration promises to address greenhouse-gas emissions by capturing carbon dioxide from the atmosphere and injecting it deep below the Earth\u2019s surface, where it would permanently solidify into rock. The U.S. Environmental Protection Agency estimates that current carbon-sequestration technologies may eliminate […]<\/p>\n","protected":false},"author":6,"featured_media":2222,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[15,17],"tags":[],"class_list":["post-2221","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-environment","category-research"],"featured_image_urls":{"full":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/01\/MIT-CO2-sequestration-01_0.jpg",639,426,false],"thumbnail":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/01\/MIT-CO2-sequestration-01_0-150x150.jpg",150,150,true],"medium":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/01\/MIT-CO2-sequestration-01_0-300x200.jpg",300,200,true],"medium_large":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/01\/MIT-CO2-sequestration-01_0.jpg",639,426,false],"large":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/01\/MIT-CO2-sequestration-01_0.jpg",639,426,false],"1536x1536":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/01\/MIT-CO2-sequestration-01_0.jpg",639,426,false],"2048x2048":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/01\/MIT-CO2-sequestration-01_0.jpg",639,426,false],"ultp_layout_landscape_large":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/01\/MIT-CO2-sequestration-01_0.jpg",639,426,false],"ultp_layout_landscape":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/01\/MIT-CO2-sequestration-01_0.jpg",639,426,false],"ultp_layout_portrait":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/01\/MIT-CO2-sequestration-01_0.jpg",600,400,false],"ultp_layout_square":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/01\/MIT-CO2-sequestration-01_0.jpg",600,400,false],"newspaper-x-single-post":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/01\/MIT-CO2-sequestration-01_0.jpg",639,426,false],"newspaper-x-recent-post-big":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/01\/MIT-CO2-sequestration-01_0.jpg",540,360,false],"newspaper-x-recent-post-list-image":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/01\/MIT-CO2-sequestration-01_0.jpg",95,63,false],"web-stories-poster-portrait":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/01\/MIT-CO2-sequestration-01_0.jpg",639,426,false],"web-stories-publisher-logo":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/01\/MIT-CO2-sequestration-01_0.jpg",96,64,false],"web-stories-thumbnail":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/01\/MIT-CO2-sequestration-01_0.jpg",150,100,false]},"author_info":{"info":["Amrita Tuladhar"]},"category_info":"Environment<\/a> Research<\/a>","tag_info":"Research","comment_count":"0","_links":{"self":[{"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/posts\/2221","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/users\/6"}],"replies":[{"embeddable":true,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/comments?post=2221"}],"version-history":[{"count":0,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/posts\/2221\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/media\/2222"}],"wp:attachment":[{"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/media?parent=2221"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/categories?post=2221"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/tags?post=2221"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}