{"id":23935,"date":"2023-05-12T12:33:13","date_gmt":"2023-05-12T06:48:13","guid":{"rendered":"https:\/\/www.revoscience.com\/en\/?p=23935"},"modified":"2023-05-12T12:33:15","modified_gmt":"2023-05-12T06:48:15","slug":"first-structural-analysis-of-highly-reactive-anionic-pt0-complexes","status":"publish","type":"post","link":"https:\/\/www.revoscience.com\/en\/first-structural-analysis-of-highly-reactive-anionic-pt0-complexes\/","title":{"rendered":"First Structural Analysis of Highly Reactive Anionic Pt(0) Complexes"},"content":{"rendered":"\n<figure class=\"wp-block-image size-large is-resized is-style-default\"><img loading=\"lazy\" decoding=\"async\" sizes=\"auto, (max-width: 675px) 100vw, 675px\" src=\"https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2023\/05\/press_kameo_a-675x509.png\" alt=\"\" class=\"wp-image-23936\" width=\"856\" height=\"645\" title=\"\" srcset=\"https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2023\/05\/press_kameo_a-675x509.png 675w, https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2023\/05\/press_kameo_a-530x400.png 530w, https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2023\/05\/press_kameo_a-768x579.png 768w, https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2023\/05\/press_kameo_a-154x116.png 154w, https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2023\/05\/press_kameo_a.png 1100w\" \/><figcaption class=\"wp-element-caption\"><em>Molecular structure of anionic Pt(0) complexes. Extremely unstable anionic Pt(0) complexes have been successfully stabilized by leveraging the electron-accepting ability of boron compounds. IMAGE: OMU<\/em><\/figcaption><\/figure>\n\n\n\n<p>Japan\u2014Osaka Metropolitan University scientists elucidated the molecular structure of anionic Pt(0) complexes for the first time in collaboration with co-researchers at Paul Sabatier University &#8211; Toulouse III. <\/p>\n\n\n\n<p>The key to success is the stabilization of anionic Pt(0) complexes (which are usually unstable owing to their electron-donating nature) by the electron-accepting properties of boron compounds. The research is expected to lead to the development of innovative catalytic reactions mediated by these chemical species.<\/p>\n\n\n\n<p>Anionic M<sup>0<\/sup>\u00a0complexes (M\u00a0=\u00a0group 10 metals) have attracted attention as active species for catalytic reactions; however, their molecular structures have very rarely been determined owing to their extremely high reactivity.<\/p>\n\n\n\n<p>Particularly, the structures of Pt<sup>0<\/sup>\u00a0complexes, which are expected to exhibit a high degree of reactivity, have not been determined, and their syntheses have been almost nonexistent.<\/p>\n\n\n\n<p>Associate Professor Hajime Kameo and Professor Hiroyuki Matsuzaka from the Osaka Metropolitan University Graduate School of Science and CNRS Senior Researcher Didier Bourissou (Paul Sabatier University &#8211; Toulouse III) elucidated the molecular structures of anionic Pt<sup>0<\/sup>\u00a0complexes for the first time. <\/p>\n\n\n\n<p>\u201cAlthough platinum complexes that exhibit a variety of catalytic activities have been actively studied, anionic Pt<sup>0<\/sup>\u00a0complexes have remained a mystery,\u201d stated Professor Kameo. <\/p>\n\n\n\n<p>\u201cThe results of this research not only enable us to elucidate the properties and functions of highly active chemical species but also provide new guidelines for their creation. It is expected to lead to the development of innovative catalytic reactions mediated by these chemical species.\u201d<\/p>\n\n\n\n<p>Their findings were published in <a href=\"https:\/\/doi.org\/10.1002\/anie.202301509\" target=\"_blank\" rel=\"noreferrer noopener\"><em>Angewandte Chemie International Edition<\/em><\/a>.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Osaka Metropolitan University scientists elucidated the molecular structure of anionic Pt(0) complexes for the first time in collaboration with co-researchers at Paul Sabatier University &#8211; Toulouse III. <\/p>\n","protected":false},"author":2,"featured_media":23936,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[17],"tags":[],"class_list":["post-23935","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-research"],"featured_image_urls":{"full":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2023\/05\/press_kameo_a.png",1100,830,false],"thumbnail":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2023\/05\/press_kameo_a-200x200.png",200,200,true],"medium":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2023\/05\/press_kameo_a-530x400.png",530,400,true],"medium_large":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2023\/05\/press_kameo_a-768x579.png",750,565,true],"large":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2023\/05\/press_kameo_a-675x509.png",675,509,true],"1536x1536":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2023\/05\/press_kameo_a.png",1100,830,false],"2048x2048":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2023\/05\/press_kameo_a.png",1100,830,false],"ultp_layout_landscape_large":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2023\/05\/press_kameo_a-1100x800.png",1100,800,true],"ultp_layout_landscape":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2023\/05\/press_kameo_a-870x570.png",870,570,true],"ultp_layout_portrait":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2023\/05\/press_kameo_a-600x830.png",600,830,true],"ultp_layout_square":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2023\/05\/press_kameo_a-600x600.png",600,600,true],"newspaper-x-single-post":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2023\/05\/press_kameo_a-760x490.png",760,490,true],"newspaper-x-recent-post-big":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2023\/05\/press_kameo_a-550x360.png",550,360,true],"newspaper-x-recent-post-list-image":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2023\/05\/press_kameo_a-95x65.png",95,65,true],"web-stories-poster-portrait":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2023\/05\/press_kameo_a.png",640,483,false],"web-stories-publisher-logo":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2023\/05\/press_kameo_a.png",96,72,false],"web-stories-thumbnail":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2023\/05\/press_kameo_a.png",150,113,false]},"author_info":{"info":["RevoScience"]},"category_info":"<a href=\"https:\/\/www.revoscience.com\/en\/category\/news\/research\/\" rel=\"category tag\">Research<\/a>","tag_info":"Research","comment_count":"0","_links":{"self":[{"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/posts\/23935","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/comments?post=23935"}],"version-history":[{"count":0,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/posts\/23935\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/media\/23936"}],"wp:attachment":[{"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/media?parent=23935"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/categories?post=23935"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/tags?post=23935"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}