{"id":7376,"date":"2016-01-22T04:46:38","date_gmt":"2016-01-22T04:46:38","guid":{"rendered":"http:\/\/revoscience.com\/en\/?p=7376"},"modified":"2016-01-22T04:46:38","modified_gmt":"2016-01-22T04:46:38","slug":"scientists-tune-polymer-materials-transparency","status":"publish","type":"post","link":"https:\/\/www.revoscience.com\/en\/scientists-tune-polymer-materials-transparency\/","title":{"rendered":"Scientists tune polymer material\u2019s transparency"},"content":{"rendered":"

Material may offer cheaper alternative to smart windows.<\/strong><\/em><\/span><\/p>\n

\"mit_logo.5589a465cf6b8\"<\/a>CAMBRIDGE, Mass.<\/strong> —\u00a0If you\u2019ve ever blown up a balloon or pulled at a pair of pantyhose, you may have noticed that the more the material stretches, the more transparent it becomes. It\u2019s a simple enough observation: the thinner a material, the more light shines through.\u00a0<\/span><\/p>\n

Now MIT scientists have come up with a theory to predict exactly how much light is transmitted through a material, given its thickness and degree of stretch. Using this theory, they accurately predicted the changing transparency of a rubber-like polymer structure as it was stretched like a spring and inflated like a balloon.\u00a0<\/span><\/p>\n

Francisco L\u00f3pez Jim\u00e9nez, a postdoc in MIT\u2019s Department of Civil and Environmental Engineering, says the researchers\u2019 experimental polymer structure and their predictive understanding of it may be useful in the design of cheaper materials for smart windows \u2014 surfaces that automatically adjust the amount of incoming light.\u00a0<\/span><\/p>\n

\u201cFor buildings and windows that automatically react to light, you don\u2019t have to spend as much on heating and air conditioning,\u201d L\u00f3pez Jim\u00e9nez says. \u201cThe problem is, these materials are too expensive to produce for every window in a building. Our idea was to look for a simpler and cheaper way to let through more or less light, by stretching a very simple material: a transparent polymer that is readily available.\u201d<\/span><\/p>\n

[pullquote]The researchers set out to fabricate a type of soft color composite \u2014 a material that changes color or transparency in response to external stimuli, such as electrical, chemical, or mechanical force.[\/pullquote]<\/p>\n

L\u00f3pez Jim\u00e9nez envisions covering window surfaces with several layers of the polymer structure. He says designers could use the group\u2019s equation to determine the amount of force to apply to a polymer layer to effectively tune the amount of incoming light.\u00a0<\/span><\/p>\n

The research team \u2014 which includes L\u00f3pez Jim\u00e9nez; Pedro Reis, the Gilbert W. Winslow CD Associate Professor of Civil and Environmental Engineering and Mechanical Engineering; and Shanmugam Kumar of the Masdar Institute of Science and Technology in Abu Dhabi \u2014 has published its results this week in the journal\u00a0Advanced Optical Materials.<\/em><\/span><\/p>\n

Stacking the polymer deck<\/strong><\/span><\/p>\n

The current work arose from a related project by Reis, L\u00f3pez Jim\u00e9nez, and Kumar, in which they analyzed the light-transmitting properties of a simple block of PDMS \u2014 a widely used rubbery, transparent polymer. The polymer block contained some darkened regions, and the team was looking to see how deforming the block would change the light traveling through the material.\u00a0<\/span><\/p>\n

\u201cIt was a happy accident,\u201d L\u00f3pez Jim\u00e9nez says. \u201cWe were just playing with the material, and we soon got interested in how we can predict this and get the numbers right.\u201d\u00a0<\/span><\/p>\n

The researchers set out to fabricate a type of soft color composite \u2014 a material that changes color or transparency in response to external stimuli, such as electrical, chemical, or mechanical force. Reis and L\u00f3pez Jim\u00e9nez created a thin, rectangular stack of transparent PDMS sheets, mixed with a solution of black, micron-sized dye particles, that may be easily stretched, or deformed mechanically. With no deformation, the structure appears opaque. As it is stretched or inflated, the material lets in more light.\u00a0<\/span><\/p>\n

In initial experiments, the researchers shone a light through the polymer structure infused with dye particles and characterized the amount of light transmitted through the material, without any deformation. They then stretched the polymer perpendicular to the direction of light and measured both the thickness of the polymer and the light coming through.\u00a0<\/span><\/p>\n

A theory on light<\/strong><\/span><\/p>\n

They compared their measurements with predictions from their equation, which they devised using the Beer-Lambert Law, a classical optics theory that describes the way light travels through\u00a0a material with given properties. The team combined this theory with their experimental analysis, and derived a simple equation to predict the amount of light transmitted through a mechanically deformed PDMS structure.\u00a0<\/span><\/p>\n

To verify their equation, Reis and L\u00f3pez Jim\u00e9nez carried out one more set of experiments, in which they clamped the PDMS structure in the shape of a disc, then inflated the material like a balloon, as they shone a light from below. They measured the amount of light coming through and found that as the material was stretched and thinned, more light came through, at exactly the same intensities that were predicted by their equation.\u00a0<\/span><\/p>\n

\u201cWe can predict and characterize the evolution of light as we strain it,\u201d L\u00f3pez Jim\u00e9nez says. \u201cIf you give me the initial material properties and measure the incoming light intensity, we know exactly how much light will go through with deformation.\u201d\u00a0<\/span><\/p>\n

He adds that going forward, he hopes to use the equation to help tune the transparency and optical transmittance of materials with more complex surfaces and textures.\u00a0<\/span><\/p>\n

\u201cSoft color composites offer exciting opportunities to provide materials with switchable and tunable optical properties,\u201d Reis says. \u201cApplying this relatively simple but both robust and predictable mechanism is an exciting challenge worth pursuing for concrete engineering applications such as indoor light control through smart windows.\u201d<\/span><\/p>\n

This work was supported by the Cooperative Agreement between the Masdar and MIT.<\/span><\/p>\n","protected":false},"excerpt":{"rendered":"

MIT scientists have come up with a theory to predict exactly how much light is transmitted through a material, given its thickness and degree of stretch.<\/p>\n","protected":false},"author":6,"featured_media":4857,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[17],"tags":[],"class_list":["post-7376","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-research"],"featured_image_urls":{"full":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/06\/mit_logo.5589a465cf6b8.jpg",640,360,false],"thumbnail":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/06\/mit_logo.5589a465cf6b8-150x150.jpg",150,150,true],"medium":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/06\/mit_logo.5589a465cf6b8-300x168.jpg",300,168,true],"medium_large":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/06\/mit_logo.5589a465cf6b8.jpg",640,360,false],"large":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/06\/mit_logo.5589a465cf6b8.jpg",640,360,false],"1536x1536":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/06\/mit_logo.5589a465cf6b8.jpg",640,360,false],"2048x2048":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/06\/mit_logo.5589a465cf6b8.jpg",640,360,false],"ultp_layout_landscape_large":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/06\/mit_logo.5589a465cf6b8.jpg",640,360,false],"ultp_layout_landscape":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/06\/mit_logo.5589a465cf6b8.jpg",640,360,false],"ultp_layout_portrait":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/06\/mit_logo.5589a465cf6b8.jpg",600,338,false],"ultp_layout_square":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/06\/mit_logo.5589a465cf6b8.jpg",600,338,false],"newspaper-x-single-post":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/06\/mit_logo.5589a465cf6b8.jpg",640,360,false],"newspaper-x-recent-post-big":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/06\/mit_logo.5589a465cf6b8.jpg",550,309,false],"newspaper-x-recent-post-list-image":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/06\/mit_logo.5589a465cf6b8.jpg",95,53,false],"web-stories-poster-portrait":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/06\/mit_logo.5589a465cf6b8.jpg",640,360,false],"web-stories-publisher-logo":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/06\/mit_logo.5589a465cf6b8.jpg",96,54,false],"web-stories-thumbnail":["https:\/\/www.revoscience.com\/en\/wp-content\/uploads\/2015\/06\/mit_logo.5589a465cf6b8.jpg",150,84,false]},"author_info":{"info":["Amrita Tuladhar"]},"category_info":"Research<\/a>","tag_info":"Research","comment_count":"0","_links":{"self":[{"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/posts\/7376","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/users\/6"}],"replies":[{"embeddable":true,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/comments?post=7376"}],"version-history":[{"count":0,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/posts\/7376\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/media\/4857"}],"wp:attachment":[{"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/media?parent=7376"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/categories?post=7376"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.revoscience.com\/en\/wp-json\/wp\/v2\/tags?post=7376"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}